Non-linear dilational rheology of liquid-liquid interfaces stabilized by dipeptide hydrogels
نویسندگان
چکیده
Abstract We investigate the effects of salt concentration on rheological properties dipeptide hydrogel fibres at liquid-liquid interfaces. The interfaces were subjected to large amplitude oscillatory dilation (LAOD) experiments across a range oscillation strains and frequencies. Lissajous plots pressure-strain used for characterizing viscoelastic identifying apparent yielding. show that key aspects response vary significantly with concentration. At low strain, independent concentration, curves an almost elliptical shape. As strain is increased, asymmetry in evidences non-linear response. departure from ellipse most obvious negative (at moderate high concentrations) suggestive strain-hardening compression. tilt towards diagonal elevated demonstrating are becoming increasingly elastic. However, increasing frequency has little systematic effect. infer addition leads development structure our observations elastic To fully capture behaviour, we suggest modification analysis calculate ratio S quantify degree non-linearities figures, so as better reveal presence instant strain-softening responses.
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ژورنال
عنوان ژورنال: Rheologica Acta
سال: 2022
ISSN: ['0035-4511', '1435-1528']
DOI: https://doi.org/10.1007/s00397-022-01380-x